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Protonated bisphosphines: a new class of powerful hydride donors capable of CO2 reduction. (Chemical Communication, in print, https://doi.org/10.1039/D5CC06952A)

19.2.2026.
Protonated bisphosphines: a new class of powerful hydride donors capable of CO2 reduction. (Chemical Communication, in print, https://doi.org/10.1039/D5CC06952A)

DOI: https://doi.org/10.1039/D5CC06952A

DFT calculations reveal that proton-sponge-like monoprotonated bisphosphines are exceptionally strong hydride donors, in some cases surpassing Super-Hydride. This work establishes a new design principle for metal-free hydride donors and highlights their potential for CO2 reduction.

Bis-fosfini kao nemetalni katalizatori za aktivaciju malih molekula – dizajn i sinteza